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Iron-catalyzed α-C–H functionalization of π-bonds: cross-dehydrogenative coupling and mechanistic insights

The deprotonation of propargylic C–H bonds for subsequent functionalization typically requires stoichiometric metal alkyl or amide reagents. In addition to the undesirable generation of stoichiometric metallic waste, these conditions limit the functional group compatibility and versatility of this f...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Wang, Yidong, Zhu, Jin, Guo, Rui, Lindberg, Haley, Wang, Yi-Ming
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163013/
https://ncbi.nlm.nih.gov/pubmed/34094439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05091a
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