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Development and mechanistic investigation of the manganese(iii) salen-catalyzed dehydrogenation of alcohols

The first example of a manganese(iii) catalyst for the acceptorless dehydrogenation of alcohols is presented. N,N′-Bis(salicylidene)-1,2-cyclohexanediaminomanganese(iii) chloride (2) has been shown to catalyze the direct synthesis of imines from a variety of alcohols and amines with the liberation o...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Samuelsen, Simone V., Santilli, Carola, Ahlquist, Mårten S. G., Madsen, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6349018/
https://ncbi.nlm.nih.gov/pubmed/30774913
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03969k
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