Site of Azido Substitution in the Sugar Moiety of Azidopyrimidine Nucleosides Influences the Reactivity of Aminyl Radicals Formed by Dissociative Electron Attachment

In this work, electron-induced site-specific formation of neutral π-type aminyl radicals (RNH•) and their reactions with pyrimidine nucleoside analogs azidolabeled at various positions in the sugar moiety, e.g., at 2′-, 3′-, 4′-, and 5′- sites along with a model compound 3-azido-1-propanol (3AZPrOH)...

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Detalhes bibliográficos
Publicado no:J Phys Chem B
Main Authors: Mudgal, Mukesh, Dang, Thao P., Sobczak, Adam J., Lumpuy, Daniel A., Dutta, Priya, Ward, Samuel, Ward, Katherine, Alahmadi, Moaadh, Kumar, Anil, Sevilla, Michael D., Wnuk, Stanislaw F., Adhikary, Amitava
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7746630/
https://ncbi.nlm.nih.gov/pubmed/33270461
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.0c08201
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