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Site of Azido Substitution in the Sugar Moiety of Azidopyrimidine Nucleosides Influences the Reactivity of Aminyl Radicals Formed by Dissociative Electron Attachment
In this work, electron-induced site-specific formation of neutral π-type aminyl radicals (RNH•) and their reactions with pyrimidine nucleoside analogs azidolabeled at various positions in the sugar moiety, e.g., at 2′-, 3′-, 4′-, and 5′- sites along with a model compound 3-azido-1-propanol (3AZPrOH)...
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| Veröffentlicht in: | J Phys Chem B |
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| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7746630/ https://ncbi.nlm.nih.gov/pubmed/33270461 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.0c08201 |
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