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Pd-catalyzed γ-C(sp(3))–H Fluorination of Free Amines
The first example of free amine γ-C(sp(3))–H fluorination is realized using 2-hydroxynicotinaldehyde as the transient directing group. A wide range of cyclohexyl and linear aliphatic amines could be fluorinated selectively at the γ-methyl and methylene positions. Electron withdrawing 3,5-disubstitut...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7685760/ https://ncbi.nlm.nih.gov/pubmed/32363869 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b13537 |
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