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Nickel-Catalyzed Insertions of Vinylidenes into Si–H Bonds
A nickel-catalyzed reductive cyclization of 1,1-dichloroalkenyl silanes is reported. The products of this reaction are unsaturated five- or six-membered silacycles. Intermolecular variants are also described, providing access to trisubstituted vinyl silanes that are not accessible by alkyne hydrosil...
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| Pubblicato in: | Chem Commun (Camb) |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7679053/ https://ncbi.nlm.nih.gov/pubmed/33141128 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc05970f |
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