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Nickel-Catalyzed Insertions of Vinylidenes into Si–H Bonds

A nickel-catalyzed reductive cyclization of 1,1-dichloroalkenyl silanes is reported. The products of this reaction are unsaturated five- or six-membered silacycles. Intermolecular variants are also described, providing access to trisubstituted vinyl silanes that are not accessible by alkyne hydrosil...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Commun (Camb)
Main Authors: Biswas, Sourish, Pal, Sudipta, Uyeda, Christopher
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7679053/
https://ncbi.nlm.nih.gov/pubmed/33141128
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc05970f
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