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Enantioselective Diarylcarbene Insertion into Si–H Bonds Induced by Electronic Properties of the Carbenes
Catalytic enantioselection usually depends on differences in steric interactions between prochiral substrates and a chiral catalyst. We have discovered a carbene Si–H insertion in which the enantioselectivity depends primarily on the electronic characteristics of the carbene substrate, and the log(e...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7605718/ https://ncbi.nlm.nih.gov/pubmed/32539369 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04725 |
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