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Enantioselective carbene insertion into the N–H bond of benzophenone imine
Efficient enantioselective insertion of α-diazoesters into the N–H bond of N-sp(2)-hybridized benzophenone imine was realized by using Rh(2)(esp)(2) and chiral guanidine cooperative catalysis. Both aliphatic and aromatic substituted α-amino esters were obtained in high yields (up to 99%) and good en...
Shranjeno v:
| izdano v: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6979361/ https://ncbi.nlm.nih.gov/pubmed/32110317 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03354h |
| Oznake: |
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