Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene

The reaction of [Ni(Mes(2)Im)(2)] (1) (Mes(2)Im = 1,3-dimesityl-imidazolin-2-ylidene) with polyfluorinated arenes as well as mechanistic investigations concerning the insertion of 1 and [Ni((i)Pr(2)Im)(2)] (1ipr) ((i)Pr(2)Im = 1,3-diisopropyl-imidazolin-2-ylidene) into the C–F bond of C(6)F(6) is re...

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Detalles Bibliográficos
Publicado en:Chem Sci
Autores principales: Kuntze-Fechner, Maximilian W., Verplancke, Hendrik, Tendera, Lukas, Diefenbach, Martin, Krummenacher, Ivo, Braunschweig, Holger, Marder, Todd B., Holthausen, Max C., Radius, Udo
Formato: Artigo
Lenguaje:Inglês
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162383/
https://ncbi.nlm.nih.gov/pubmed/34094350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04237d
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