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A T-shaped Ni[κ(2)-(CF(2))(4)–] NHC complex: unusual C(sp(3))–F and M–C(F) bond functionalization reactions
A T-shaped octafluoronickelacyclopentane–NHC complex is prepared and characterized. While the solid-state structure includes a weak isopropyl-CH(3) agostic interaction, the reactivity of this complex with Lewis- and Brønsted acids is clearly enhanced by its low coordination number. Reaction with Me(...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6054117/ https://ncbi.nlm.nih.gov/pubmed/30090259 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01886b |
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