A T-shaped Ni[κ(2)-(CF(2))(4)–] NHC complex: unusual C(sp(3))–F and M–C(F) bond functionalization reactions

A T-shaped octafluoronickelacyclopentane–NHC complex is prepared and characterized. While the solid-state structure includes a weak isopropyl-CH(3) agostic interaction, the reactivity of this complex with Lewis- and Brønsted acids is clearly enhanced by its low coordination number. Reaction with Me(...

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Vydáno v:Chem Sci
Hlavní autoři: Andrella, Nicholas O., Sicard, Alexandre J., Gorelsky, Serge I., Korobkov, Ilia, Baker, R. Tom
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2015
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054117/
https://ncbi.nlm.nih.gov/pubmed/30090259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01886b
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