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Nickel Catalyzed Vinylidene Insertions into O–H Bonds

A (pybox)Ni catalyst (pybox = pyridine–bis(oxazoline)) promotes the reductive cyclization of β-hydroxy 1,1-dichloroalkenes to form 2,3-dihydrofurans. The substrates for this reaction are conveniently prepared by an aldol addition followed by one-carbon homologation. Chiral substrates are accessible...

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Detalles Bibliográficos
Publicado en:ACS Catal
Main Authors: Kang, Houng, Uyeda, Christopher
Formato: Artigo
Idioma:Inglês
Publicado: 2020
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8115312/
https://ncbi.nlm.nih.gov/pubmed/33996195
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c04713
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