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Synthesis of (−)‐Dihydroraputindole D by Enantioselective Benzoylation of a 1,3‐Diol Intermediate
The enantioselective synthesis of (−)‐dihydroraputindole D is reported. The key step is the desymmetrizing benzoylation of a prochiral 1,3‐diol employing Trost′s ProPhenol catalyst system, which has been applied for the first time to a cyclic molecule carrying geminal hydroxymethyl groups. The cyclo...
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| Publicado no: | Chemistry |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7590097/ https://ncbi.nlm.nih.gov/pubmed/32725857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002579 |
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