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Regioselective Benzoylation of Diols and Carbohydrates by Catalytic Amounts of Organobase

A novel metal-free organobase-catalyzed regioselective benzoylation of diols and carbohydrates has been developed. Treatment of diol and carbohydrate substrates with 1.1 equiv. of 1-benzoylimidazole and 0.2 equiv. of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in MeCN under mild conditions resulted in...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Lu, Yuchao, Hou, Chenxi, Ren, Jingli, Xin, Xiaoting, Xu, Hengfu, Pei, Yuxin, Dong, Hai, Pei, Zhichao
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6274181/
https://ncbi.nlm.nih.gov/pubmed/27196888
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21050641
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