BIMP‐Catalyzed 1,3‐Prototropic Shift for the Highly Enantioselective Synthesis of Conjugated Cyclohexenones

A bifunctional iminophosphorane (BIMP)‐catalysed enantioselective synthesis of α,β‐unsaturated cyclohexenones through a facially selective 1,3‐prototropic shift of β,γ‐unsaturated prochiral isomers, under mild reaction conditions and in short reaction times, on a range of structurally diverse substr...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Golec, Jonathan C., Carter, Eve M., Ward, John W., Whittingham, William G., Simón, Luis, Paton, Robert S., Dixon, Darren J.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540019/
https://ncbi.nlm.nih.gov/pubmed/32558981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006202
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