Fluorine‐Induced Pseudo‐Anomeric Effects in Methoxycyclohexanes through Electrostatic 1,3‐Diaxial Interactions

We report counter‐intuitive axial preferences in non‐stereochemically biased, selectively fluorinated methoxycyclohexanes. These pseudo‐anomeric effects are apparent when electronegative CF(2) groups are placed at the C‐2, C‐4 and C‐6 positions of the cyclohexane ring to render the C‐3/5 axial hydro...

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發表在:Chemistry
Main Authors: Piscelli, Bruno A., Sanders, William, Yu, Cihang, Al Maharik, Nawaf, Lebl, Thomas, Cormanich, Rodrigo A., O'Hagan, David
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2020
主題:
Communications
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540582/
https://ncbi.nlm.nih.gov/pubmed/32588927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003058
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