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Fluorine-containing substituents: metabolism of the α,α-difluoroethyl thioether motif

We report the metabolism of the recently introduced α,α-difluoroethyl thioether motif to explore further its potential as a substituent for bioactives discovery chemistry. Incubation of two aryl–SCF(2)CH(3) ethers with the model yeast organism Cunninghamella elegans, indicates that the sulfur of the...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Rodil, Andrea, Slawin, Alexandra M Z, Al-Maharik, Nawaf, Tomita, Ren, O’Hagan, David
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6604701/
https://ncbi.nlm.nih.gov/pubmed/31293694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.144
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