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Lewis acid-promoted hydrofluorination of alkynyl sulfides to generate α-fluorovinyl thioethers
A new method for the preparation of α-fluorovinyl thioethers is reported which involves the hydrofluorination of alkynyl sulfides with 3HF·Et(3)N, a process that requires Lewis acid activation using BF(3)·Et(2)O and TiF(4). The method gives access to a range of α-fluorovinyl thioethers, some in high...
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| Izdano u: | Beilstein J Org Chem |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Beilstein-Institut
2015
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4661019/ https://ncbi.nlm.nih.gov/pubmed/26664609 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.205 |
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