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Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles

The Prins reaction was investigated using BF(3)·OEt(2) as a Lewis acid. It has been recently demonstrated, that if BF(3)·OEt(2) is used in stoichiometric amounts then these reactions generate fluorinated products where the BF(3)·OEt(2) contributes fluoride ion to quench the intermediate carbocations...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Launay, Guillaume G, Slawin, Alexandra M Z, O'Hagan, David
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2010
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2874316/
https://ncbi.nlm.nih.gov/pubmed/20502655
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.41
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