Fluorine‐Induced Pseudo‐Anomeric Effects in Methoxycyclohexanes through Electrostatic 1,3‐Diaxial Interactions

We report counter‐intuitive axial preferences in non‐stereochemically biased, selectively fluorinated methoxycyclohexanes. These pseudo‐anomeric effects are apparent when electronegative CF(2) groups are placed at the C‐2, C‐4 and C‐6 positions of the cyclohexane ring to render the C‐3/5 axial hydro...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chemistry
Egile Nagusiak: Piscelli, Bruno A., Sanders, William, Yu, Cihang, Al Maharik, Nawaf, Lebl, Thomas, Cormanich, Rodrigo A., O'Hagan, David
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2020
Gaiak:
Communications
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540582/
https://ncbi.nlm.nih.gov/pubmed/32588927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003058
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