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C(sp(2))–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp(2))–H Activation and Catalytically Relevant Intermediates
Well-defined bis(silylene)pyridine cobalt(III) precatalysts for C(sp(2))–H borylation have been synthesized and applied to the investigation of the mechanism of the catalytic borylation of furans and pyridines. Specifically, [((Ar)SiNSi)CoH(3)]·NaHBEt(3) ((Ar)SiNSi = 2,6-[EtNSi(N(t)Bu)(2)CAr](2)C(5)...
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| Vydáno v: | Organometallics |
|---|---|
| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7440285/ https://ncbi.nlm.nih.gov/pubmed/32831451 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.0c00382 |
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