Φορτώνει......
Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp(2))-H Oxidative Addition Results in ortho-to-Fluorine Selectivity
The mechanism of C(sp(2))–H borylation of fluorinated arenes with B(2)Pin(2) (Pin = pinacolato) catalyzed by bis(phosphino)pyridine ((iPr)PNP) cobalt complexes was studied to understand the origins of the uniquely high ortho-to-fluorine regioselectivity observed in these reactions. Variable time nor...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | J Am Chem Soc |
|---|---|
| Κύριοι συγγραφείς: | , , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2019
|
| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6761019/ https://ncbi.nlm.nih.gov/pubmed/31449749 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07984 |
| Ετικέτες: |
Προσθήκη ετικέτας
Δεν υπάρχουν, Καταχωρήστε ετικέτα πρώτοι!
|