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C(sp(2))–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities
Cobalt catalysts with electronically enhanced site selectivity have been developed, as evidenced by the high ortho-to-fluorine selectivity observed in the C(sp(2))–H borylation of fluorinated arenes. Both the air-sensitive cobalt(III) dihydride boryl 4-Me-((iPr)PNP)Co(H)(2)BPin (1) and the air-stabl...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5701518/ https://ncbi.nlm.nih.gov/pubmed/28139907 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13346 |
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