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Mechanistic Studies of Cobalt-Catalyzed C(sp(2))–H Borylation of Five-Membered Heteroarenes with Pinacolborane
Studies into the mechanism of cobalt-catalyzed C(sp(2))−H borylation of five-membered heteroarenes with pinacolborane (HBPin) as the boron source established the catalyst resting state as the trans-cobalt(III) dihydride boryl, ((iPr)PNP)Co(H)(2)(BPin) ((iPr)PNP = 2,6-((i)Pr(2)PCH(2))(2)(C(5)H(3)N)),...
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| Publicado en: | ACS Catal |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5822728/ https://ncbi.nlm.nih.gov/pubmed/29479489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b01151 |
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