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Cobalt Pincer Complexes in Catalytic C-H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes

The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigated by density functional theory calculations. Experimental observations identified trans-((iPr)PNP)CoH(2)(BPin) as the resting state in the borylation of five-membered heteroarenes, and 4-BPin-((iPr)PN...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Li, Haixia, Obligacion, Jennifer V., Chirik, Paul J., Hall, Michael B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6358283/
https://ncbi.nlm.nih.gov/pubmed/30719402
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b03146
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