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Cobalt Pincer Complexes in Catalytic C-H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes
The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigated by density functional theory calculations. Experimental observations identified trans-((iPr)PNP)CoH(2)(BPin) as the resting state in the borylation of five-membered heteroarenes, and 4-BPin-((iPr)PN...
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| Publicat a: | ACS Catal |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6358283/ https://ncbi.nlm.nih.gov/pubmed/30719402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b03146 |
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