Synthesis of 5-(Fluoroalkyl)isoxazole Building Blocks by Regioselective Reactions of Functionalized Halogenoximes

A comprehensive study on the synthesis of 5-fluoroalkyl-substituted isoxazoles starting from functionalized halogenoximes is reported. One-pot metal-free [3+2] cycloaddition of CF(3)-substituted alkenes and halogenoximes bearing ester, bromo, chloromethyl, and protected amino groups was developed fo...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Chalyk, Bohdan A., Hrebeniuk, Kateryna V., Fil, Yulia V., Gavrilenko, Konstantin S., Rozhenko, Alexander B., Vashchenko, Bohdan V., Borysov, Oleksandr V., Biitseva, Angelina V., Lebed, Pavlo S., Bakanovych, Iulia, Moroz, Yurii S., Grygorenko, Oleksandr O.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7341682/
https://ncbi.nlm.nih.gov/pubmed/31626546
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02264
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