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On the Crucial Role of Isolated Electronic States in the Thermal Reaction of ReC(+) with Dihydrogen

Presented here is that isolated, long‐lived electronic states of ReC(+) serve as the root cause for distinctly different reactivities of this diatomic ion in the thermal activation of dihydrogen. Detailed high‐level quantum chemical calculations support the experimental findings obtained in the high...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Li, Jilai, Geng, Caiyun, Weiske, Thomas, Schwarz, Helmut
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317438/
https://ncbi.nlm.nih.gov/pubmed/32181571
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001599
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