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On the Crucial Role of Isolated Electronic States in the Thermal Reaction of ReC(+) with Dihydrogen

Presented here is that isolated, long‐lived electronic states of ReC(+) serve as the root cause for distinctly different reactivities of this diatomic ion in the thermal activation of dihydrogen. Detailed high‐level quantum chemical calculations support the experimental findings obtained in the high...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Li, Jilai, Geng, Caiyun, Weiske, Thomas, Schwarz, Helmut
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317438/
https://ncbi.nlm.nih.gov/pubmed/32181571
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001599
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