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On the Crucial Role of Isolated Electronic States in the Thermal Reaction of ReC(+) with Dihydrogen

Presented here is that isolated, long‐lived electronic states of ReC(+) serve as the root cause for distinctly different reactivities of this diatomic ion in the thermal activation of dihydrogen. Detailed high‐level quantum chemical calculations support the experimental findings obtained in the high...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Li, Jilai, Geng, Caiyun, Weiske, Thomas, Schwarz, Helmut
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317438/
https://ncbi.nlm.nih.gov/pubmed/32181571
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001599
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