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Complete cleavage of the N≡N triple bond by Ta(2)N(+) via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle
An unprecedented, spontaneous, and complete cleavage of the triple bond of N(2) in the thermal reaction of (15)N(2) with Ta(2)(14)N(+) was observed experimentally by Fourier transform ion cyclotron resonance mass spectrometry; mechanistic aspects of the degenerate ligand exchange were addressed by h...
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| I publikationen: | Proc Natl Acad Sci U S A |
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| Huvudupphovsmän: | , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
National Academy of Sciences
2019
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6815182/ https://ncbi.nlm.nih.gov/pubmed/31591230 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1913664116 |
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