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A Reaction‐Induced Localization of Spin Density Enables Thermal C−H Bond Activation of Methane by Pristine FeC(4) (+)
The reactivity of the cationic metal‐carbon cluster FeC(4) (+) towards methane has been studied experimentally using Fourier‐transform ion cyclotron resonance mass spectrometry and computationally by high‐level quantum chemical calculations. At room temperature, FeC(4)H(+) is formed as the main ioni...
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| I publikationen: | Chemistry |
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| Huvudupphovsmän: | , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
John Wiley and Sons Inc.
2019
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6852486/ https://ncbi.nlm.nih.gov/pubmed/31268193 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902572 |
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