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Cobalt-Catalyzed Hydrogen Atom Transfer Induces Bicyclizations that Tolerate Electron-rich and –deficient Intermediate Alkenes
A novel Co(II)-catalyzed polyene cyclization was developed that is uniquely effective when performed in hexafluoroisopropanol as solvent. The process is presumably initiated by metal-catalyzed hydrogen atom transfer (MHAT) to 1,1-disubstituted or monosubstituted alkenes, and the reaction is remarkab...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7124983/ https://ncbi.nlm.nih.gov/pubmed/31991035 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000252 |
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