Načítá se...

Cobalt-Catalyzed Hydrogen Atom Transfer Induces Bicyclizations that Tolerate Electron-rich and –deficient Intermediate Alkenes

A novel Co(II)-catalyzed polyene cyclization was developed that is uniquely effective when performed in hexafluoroisopropanol as solvent. The process is presumably initiated by metal-catalyzed hydrogen atom transfer (MHAT) to 1,1-disubstituted or monosubstituted alkenes, and the reaction is remarkab...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Vrubliauskas, Darius, Vanderwal, Christopher D.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7124983/
https://ncbi.nlm.nih.gov/pubmed/31991035
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000252
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!