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Cobalt-Catalyzed [2π + 2π] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates
[Image: see text] Aryl-substituted bis(imino)pyridine cobalt dinitrogen compounds, ((R)PDI)CoN(2), are effective precatalysts for the intramolecular [2π + 2π] cycloaddition of α,ω-dienes to yield the corresponding bicyclo[3.2.0]heptane derivatives. The reactions proceed under mild thermal conditions...
में बचाया:
| में प्रकाशित: | J Am Chem Soc |
|---|---|
| मुख्य लेखकों: | , , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
American Chemical
Society
2015
|
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5633266/ https://ncbi.nlm.nih.gov/pubmed/26030841 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04034 |
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