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Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex
The high-valent nickel(iii) complex Ni(pyalk)(2)(+) (2) was prepared by oxidation of a nickel(ii) complex, Ni(pyalk)(2) (1) (pyalk = 2-pyridyl-2-propanoate). 2 and derivatives were fully characterized by mass spectrometry and X-ray crystallography. Electron paramagnetic resonance spectroscopy and X-...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7069233/ https://ncbi.nlm.nih.gov/pubmed/32206289 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05565g |
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