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Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

The high-valent nickel(iii) complex Ni(pyalk)(2)(+) (2) was prepared by oxidation of a nickel(ii) complex, Ni(pyalk)(2) (1) (pyalk = 2-pyridyl-2-propanoate). 2 and derivatives were fully characterized by mass spectrometry and X-ray crystallography. Electron paramagnetic resonance spectroscopy and X-...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fisher, Katherine J., Feuer, Margalit L., Lant, Hannah M. C., Mercado, Brandon Q., Crabtree, Robert H., Brudvig, Gary W.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7069233/
https://ncbi.nlm.nih.gov/pubmed/32206289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05565g
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