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Total synthesis and evaluation of C25-benzyloxyepothilone C for tubulin assembly and cytotoxicity against MCF-7 breast cancer cells

The total synthesis of C25-benzyloxy epothilone C is described. A sequential Suzuki–Aldol–Yamaguchi macrolactonization strategy was utilized employing a novel derivatized C8–C12 fragment. The C25-benzyloxy analog exhibited significantly reduced biological activity in microtubule assembly and cytotox...

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Publicat a:Bioorg Med Chem Lett
Autors principals: Hutt, Oliver E., Reddy, Bollu S., Nair, Sajiv K., Reiff, Emily A., Henri, John T., Greiner, Jack F., Chiu, Ting-Lan, VanderVelde, David G., Amin, Elizabeth A., Himes, Richard H., Georg, Gunda I.
Format: Artigo
Idioma:Inglês
Publicat: 2008
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7047897/
https://ncbi.nlm.nih.gov/pubmed/18684624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2008.07.024
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