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Migratory aptitudes in rearrangements of destabilized vinyl cations
The Lewis acid-promoted generation of destabilized vinyl cations from β-hydroxy diazo ketones leads to an energetically favorable 1,2-shift across the alkene followed by an irreversible C-H insertion to give cyclopentenone products. This reaction sequence overcomes typical challenges of counter ion...
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| 出版年: | J Org Chem |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7045800/ https://ncbi.nlm.nih.gov/pubmed/31747287 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02130 |
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