Loading...
Migratory aptitudes in rearrangements of destabilized vinyl cations
The Lewis acid-promoted generation of destabilized vinyl cations from β-hydroxy diazo ketones leads to an energetically favorable 1,2-shift across the alkene followed by an irreversible C-H insertion to give cyclopentenone products. This reaction sequence overcomes typical challenges of counter ion...
Na minha lista:
| Udgivet i: | J Org Chem |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7045800/ https://ncbi.nlm.nih.gov/pubmed/31747287 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02130 |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|