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Spectroscopic and Computational Comparisons of Thiolate-Ligated Ferric Nonheme Complexes to Cysteine Dioxygenase: Second-Sphere Effects on Substrate (Analogue) Positioning

Parallel spectroscopic and computational studies of iron(III) cysteine dioxygenase (CDO) and synthetic models are presented. The synthetic complexes utilize the ligand tris(4,5-diphenyl-1-methylimidazol-2-yl)phosphine ((Ph2)TIP), which mimics the facial three-histidine triad of CDO and other thiol d...

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Dettagli Bibliografici
Pubblicato in:Inorg Chem
Autori principali: Fischer, Anne A., Miller, Joshua R., Jodts, Richard J., Ekanayake, Danushka M., Lindeman, Sergey V., Brunold, Thomas C., Fiedler, Adam T.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6956612/
https://ncbi.nlm.nih.gov/pubmed/31789510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02432
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