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Structural, Spectroscopic, and Electrochemical Properties of Nonheme Fe(II)-Hydroquinonate Complexes: Synthetic Models of Hydroquinone Dioxygenases

Using the tris(3,5-diphenylpyrazol-1-yl)borate ((Ph2)Tp) supporting ligand, a series of mono- and dinuclear ferrous complexes containing hydroquinonate (HQate) ligands have been prepared and structurally characterized with X-ray crystallography. The monoiron(II) complexes serve as faithful mimics of...

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Detalhes bibliográficos
Main Authors: Baum, Amanda E., Park, Heaweon, Wang, Denan, Lindeman, Sergey V., Fiedler, Adam T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3891569/
https://ncbi.nlm.nih.gov/pubmed/22930005
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2dt31504a
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