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A Synthetic Model of the Nonheme Iron-Superoxo Intermediate of Cysteine Dioxygenase
A nonheme Fe(II) complex (1) that models substrate-bound cysteine dioxygenase (CDO) reacts with O(2) at −80 °C to yield a purple intermediate (2). Analysis with spectroscopic and computational methods determined that 2 features a thiolate-ligated Fe(III) center bound to a superoxide radical, mimicki...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6201693/ https://ncbi.nlm.nih.gov/pubmed/30246208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc06247a |
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