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Nonheme Iron-Thiolate Complexes as Structural Models of Sulfoxide Synthase Active Sites

Two mononuclear iron(II)–thiolate complexes have been prepared that represent structural models of the nonheme iron enzymes EgtB and OvoA, which catalyze the O(2)-dependent formation of carbon-sulfur bonds in the biosynthesis of thiohistidine compounds. The series of Fe(II) complexes reported here f...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Ekanayake, Danushka M., Fischer, Anne A., Elwood, Maya E., Guzek, Alexandra M., Lindeman, Sergey V., Popescu, Codrina V., Fiedler, Adam T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7781232/
https://ncbi.nlm.nih.gov/pubmed/33241840
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0dt03403g
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