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Nonheme Iron-Thiolate Complexes as Structural Models of Sulfoxide Synthase Active Sites

Two mononuclear iron(II)–thiolate complexes have been prepared that represent structural models of the nonheme iron enzymes EgtB and OvoA, which catalyze the O(2)-dependent formation of carbon-sulfur bonds in the biosynthesis of thiohistidine compounds. The series of Fe(II) complexes reported here f...

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發表在:Dalton Trans
Main Authors: Ekanayake, Danushka M., Fischer, Anne A., Elwood, Maya E., Guzek, Alexandra M., Lindeman, Sergey V., Popescu, Codrina V., Fiedler, Adam T.
格式: Artigo
語言:Inglês
出版: 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7781232/
https://ncbi.nlm.nih.gov/pubmed/33241840
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0dt03403g
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