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Why do thioureas and squaramides slow down the Ireland–Claisen rearrangement?
A range of chiral hydrogen-bond-donating organocatalysts was tested in the Ireland–Claisen rearrangement of silyl ketene acetals. None of these organocatalysts was able to impart any enantioselectivity on the rearrangements. Furthermore, these organocatalysts slowed down the Ireland–Claisen rearrang...
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| Publicat a: | Beilstein J Org Chem |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6941421/ https://ncbi.nlm.nih.gov/pubmed/31921366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.290 |
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