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Why do thioureas and squaramides slow down the Ireland–Claisen rearrangement?
A range of chiral hydrogen-bond-donating organocatalysts was tested in the Ireland–Claisen rearrangement of silyl ketene acetals. None of these organocatalysts was able to impart any enantioselectivity on the rearrangements. Furthermore, these organocatalysts slowed down the Ireland–Claisen rearrang...
保存先:
| 出版年: | Beilstein J Org Chem |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Beilstein-Institut
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6941421/ https://ncbi.nlm.nih.gov/pubmed/31921366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.290 |
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