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Attempts to Improve the Overall Stereoselectivity of the Ireland-Claisen Rearrangement
[Image: see text] With focus on the steric effects present in the transition states for the [3,3]-sigmatropic rearrangement, the substrate 5 was designed to improve the overall stereoselectivity of the Ireland-Claisen rearrangement. Experimentally, it was found that: (1) only Z-6 rearranges to 7 at...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2659616/ https://ncbi.nlm.nih.gov/pubmed/19128191 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8027225 |
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