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Attempts to Improve the Overall Stereoselectivity of the Ireland-Claisen Rearrangement

[Image: see text] With focus on the steric effects present in the transition states for the [3,3]-sigmatropic rearrangement, the substrate 5 was designed to improve the overall stereoselectivity of the Ireland-Claisen rearrangement. Experimentally, it was found that: (1) only Z-6 rearranges to 7 at...

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Bibliografiska uppgifter
Huvudupphovsmän: Chen, Chi-Li, Namba, Kosuke, Kishi, Yoshito
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2009
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2659616/
https://ncbi.nlm.nih.gov/pubmed/19128191
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8027225
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