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Synthesis of γ,δ-Unsaturated Glycolic Acids via Sequenced Brook and Ireland-Claisen Rearrangements
[Image: see text] Organozinc, magnesium, and lithium nucleophiles initiate a Brook/Ireland-Claisen rearrangement sequence of allylic silyl glyoxylates resulting in formation of γ,δ-unsaturated α-silyloxy acids.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2830285/ https://ncbi.nlm.nih.gov/pubmed/20143793 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9029353 |
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