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Enantioselective Synthesis of Anti-β-Substituted γ,δ-Unsaturated Amino Acids: A Highly Selective Asymmetric Thio-Claisen Rearrangement
[Image: see text] A novel synthesis of optically active anti-1β-substituted γ,δ-unsaturated amino acids via a thio-Claisen rearrangement has been achieved. A 2,5-diphenylpyrrolidine was used as a C(2)-symmetric chiral auxiliary to control the stereochemistry, giving good yields and excellent diaster...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2654228/ https://ncbi.nlm.nih.gov/pubmed/18702500 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801657q |
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