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Synthesis of Anti-β-Substituted γ,δ-Unsaturated Amino Acids via Eschenmoser–Claisen Rearrangement
[Image: see text] Anti-β-substituted γ,δ-unsaturated amino acids have been synthesized via a novel design of the Eschenmoser–Claisen rearrangement. The rearrangement gives good isolated yields and excellent diastereoselectivity due to (Z)-N,O-ketene acetal formation and the pseudochairlike conformat...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2366803/ https://ncbi.nlm.nih.gov/pubmed/16956190 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061414l |
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